2013-1-5

下記の反応が文献調査によってわかった．

【反応式】（NC(CH3)2CN)2<->2CN(CH3)2C+N2¹⁾
【反応式】DMPO+CN(CH3)2C・<->DMPO-C(CN)(CH3)2²⁾
【反応式】CN(CH3)2C・+O2<->CN(CH3)2COO・³⁾
【反応式】2ROO・　→ 2RO・　+ O2 (R=CN(CH3)2C) ⁴⁾
【反応式】CN(CH3)2CO + C6H11NO → C10H17N2O2⁵⁾

【関連文献】
・The initiation properties of 2-cyano-2-propyl hydroperoxide in oxidation processes, Aleksandra Burghardt, Zdzis?aw Kulicki, monatshefte fur chemie / chemical monthly ,115,87(1984).⁶⁾
・Detection of alkyl, alkoxyl, an d alkyperoxyl radicals from the thermolysis of azobis(isobutyronitrile) by ESR/spi n trapping. Ev idence for double spi n adducts from liquid-phase chromatography an d mass sp ectroscopy,Edward G. Janzen , Peter H. Krygsman , David A. Lindsay , D. Larry Haire , j. am. chem. soc.,112,8279(1990).⁷⁾

【関連ノート】
AIBN由来の発生したDMPOアダクトのまとめ⁸⁾

(1)   （NC(CH₃)₂CN)₂ →   2CN(CH₃)₂C・ + N₂, ?, (反応-466).
(2)   C₆H₁₁NO + CN(CH₃)₂C・ →   C₁₀H₁₇NO, ?, (反応-497).
(3)   CN(CH₃)₂C・ + O₂ →   CN(CH₃)₂COO・, ?, (反応-469).
(4)   2CN(CH₃)₂COO・ →   2CN(CH₃)₂CO + O₂, ?, (反応-527).
(5)   CN(CH₃)₂CO + C₆H₁₁NO →   C₁₀H₁₇N₂O₂, ?, (反応-528).
(6) The initiation properties of 2-cyano-2-propyl hydroperoxide in oxidation processes
Aleksandra Burghardt, Zdzis?aw Kulicki, monatshefte fur chemie / chemical monthly ,115,87(1984).
(7) Detection of alkyl, alkoxyl, and alkyperoxyl radicals from the thermolysis of azobis(isobutyronitrile) by ESR/spin trapping. Evidence for double spin adducts from liquid-phase chromatography and mass spectroscopy
Edward G. Janzen , Peter H. Krygsman , David A. Lindsay , D. Larry Haire , j. am. chem. soc.,112,8279(1990).
(8) AIBN由来の発生したDMPOアダクトのまとめ
伊藤　智博, 研究ノート, (2013).

日時	2013-01-05
関係者（共同研究者）

🗒️ AIBN由来のラジカルとDMPOおよび酸素の反応調査