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🌡️ 📆 令和6年4月26日
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Detection of alkyl, alkoxyl, and alkyperoxyl radicals from the thermolysis of azobis(isobutyronitrile) by ESR/spin trapping. Evidence for double spin adducts from liquid-phase chromatography and mass spectroscopy

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タイトル Detection of alkyl, alkoxyl, and alkyperoxyl radicals from the thermolysis of azobis(isobutyronitrile) by ESR/spin trapping. Evidence for double spin adducts from liquid-phase chromatography and mass spectroscopy
著者 Edward G. Janzen , Peter H. Krygsman , David A. Lindsay , D. Larry Haire
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2-シアノ-2-プロピルオキシルラジカル1)のDMPOアダクトの超微細結合定数A(N)=1.266. A(H)=0.837, A(H)=0.189 mTであった

DMPO-CPO2)文献値が示されている
A(N)=1.263 mT3)
A(β)(H)= 0.84 mT4)
A(γ)(H)= 0.185 mT5)
A(γ)(H)= 0.062 mT6)

2-シアノ-2-プロピルオキシル-PBNアダクト7), 2-シアノ-2-プロピル-パーオキシル-PBNアダクト8), 2-シアノ-2-プロピル-PBNアダクト9)の超微細結合定数についても述べられている

DMPO-CPO(DMPO-OR)決定にはmassによる分析行っている

引用箇所

出典:Detection of alkyl, alkoxyl, and alkyperoxyl radicals from the thermolysis of azobis(isobutyronitrile) by ESR/spin trapping. Evidence for double spin adducts from liquid-phase chromatography and mass spectroscopy


引用元


Edward G. Janzen , Peter H. Krygsman , David A. Lindsay , D. Larry Haire . Detection of alkyl, alkoxyl, and alkyperoxyl radicals from the thermolysis of azobis(isobutyronitrile) by ESR/spin trapping. Evidence for double spin adducts from liquid-phase chromatography and mass spectroscopy. . , (参照 1899-12-30T0:0:0+09:00) .

Edward G. Janzen , Peter H. Krygsman , David A. Lindsay , D. Larry Haire (1990). Detection of alkyl, alkoxyl, and alkyperoxyl radicals from the thermolysis of azobis(isobutyronitrile) by ESR/spin trapping. Evidence for double spin adducts from liquid-phase chromatography and mass spectroscopy. j. am. chem. soc., Vol.112, 8279-0


Edward G. Janzen , Peter H. Krygsman , David A. Lindsay , D. Larry Haire , "Detection of alkyl, alkoxyl, and alkyperoxyl radicals from the thermolysis of azobis(isobutyronitrile) by ESR/spin trapping. Evidence for double spin adducts from liquid-phase chromatography and mass spectroscopy", j. am. chem. soc., Vol.112, No.23, pp.8279-0 (1990).

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